Photocatalytic Hydrogen Production From Aqueous Na2S + Cucl2 → Cus + 2 Nacl

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Exception

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Servlet.java:655)org.springframework.web.servlet.Framework
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Servlet.java:855)javax.servlet.http.Http
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Servlet.java:764)org.apache.tomcat.websocket.server.Ws
Filter.do
Filter(Ws
Filter.java:53)chemicalequations.web.controllers.Locale
Filter.do
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Filter.java:52)org.springframework.web.filter.Delegating
Filter
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Proxy.java:357)org.springframework.web.filter.Delegating
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Filter.do
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Filter.java:200)org.springframework.web.filter.Once
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Filter.java:107)Root Cause

java.io.IOException: There was an error loading the template on an earlier attempt; see cause exception.freemarker.cache.Template
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Cache.java:357)freemarker.cache.Template
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Cache.java:291)freemarker.template.Configuration.get
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Template(Configuration.java:2296)org.springframework.web.servlet.view.freemarker.Free
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View.java:364)org.springframework.web.servlet.view.freemarker.Free
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Merged
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Model(Abstract
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View.java:314)org.springframework.web.servlet.Dispatcher
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Servlet.java:764)org.apache.tomcat.websocket.server.Ws
Filter.do
Filter(Ws
Filter.java:53)chemicalequations.web.controllers.Locale
Filter.do
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Filter.java:52)org.springframework.web.filter.Delegating
Filter
Proxy.invoke
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java.lang.Illegal
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Exception: /opt/tomcat/webapps/chemical-equations-1-5d/WEB-INF/lib/spring-webmvc-5.0.4.RELEASE.jar (Too many xuất hiện files)org.apache.catalina.webresources.Abstract
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Set.java:263)org.apache.catalina.webresources.Standard
Root.get
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Internal(Standard
Root.java:281)org.apache.catalina.webresources.Cached
Resource.validate
Resource(Cached
Resource.java:128)org.apache.catalina.webresources.Cache.get
Resource(Cache.java:69)org.apache.catalina.webresources.Standard
Root.get
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Root.java:216)org.apache.catalina.webresources.Standard
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Root.java:225)org.apache.catalina.loader.Webapp
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View.java:314)org.springframework.web.servlet.Dispatcher
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Servlet.java:764)org.apache.tomcat.websocket.server.Ws
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Filter.java:53)chemicalequations.web.controllers.Locale
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java.io.File
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Exception: /opt/tomcat/webapps/chemical-equations-1-5d/WEB-INF/lib/spring-webmvc-5.0.4.RELEASE.jar (Too many mở cửa files)java.util.zip.Zip
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Archive
Resource
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Resource
Internal(Standard
Root.java:281)org.apache.catalina.webresources.Cached
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Root.java:216)org.apache.catalina.webresources.Standard
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Class
Loader
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Class
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Servlet.java:870)javax.servlet.http.Http
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Servlet.java:855)javax.servlet.http.Http
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Internal(Character
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Filter.java:200)org.springframework.web.filter.Once
Per
Request
Filter.do
Filter(Once
Per
Request
Filter.java:107)Note The full stack trace of the root cause is available in the hệ thống logs.

O/Zn
O under visible light irradiation - chiaseyhoc.com Advances (chiaseyhoc.com Publishing) 400 nm), respectively. Prepared materials were characterized using various techniques such as X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), diffuse reflectance spectroscopy (DRS) and photoluminescence (PL) spectroscopy." name="citation_abstract" />
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Photocatalytic hydrogen production from aqueous Na2SO3 + Na2S solution with B/Cu
O/Zn
O under visible light irradiation†

Paramasivan
Gomathisankar,*a Katsumasa
Hachisuka,a Hideyuki
Katsumata,a Tohru
Suzuki,b Kurihiro
Funasakacand Satoshi
Kaneco*ab

* Corresponding authors

a Department of Chemistry for Materials, Graduate School of Engineering, Mie University, Tsu, Mie, nhật bản E-mail: chemsankar79

b Environmental Preservation Center, Mie University, Tsu, Mie, japan

c Department of Atmospheric Environment, Osaka city Institute of Public Health & Environmental Sciences, Osaka 543-0026, japan

Visible light photocatalytic H2 production was successfully achieved with B/Cu
O/Zn
O in aqueous Na2S–Na2SO3 solution. Zn
O and modified Zn
Os were prepared by a simple mechanochemical technique followed by a combustion process. B-doped Zn
O showed the better H2 productivity compared with the materials doped with C, N, F, B/N, và B/F. Since it was found that in situ formed Cu
S particle interaction with B–Zn
O was 1.4 times more effective for increasing the H2 generation, the composite B/Cu
O/Zn
O was fabricated for the photocatalytic hydrogen production. It demonstrated the highest hydrogen production with 224 μmol g−1 h−1 và 933 μmol g−1 h−1 under xenon lamp irradiation with and without the cut filter (>400 nm), respectively. Prepared materials were characterized using various techniques such as X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), diffuse reflectance spectroscopy (DRS) & photoluminescence (PL) spectroscopy.